Antioxidant Activity of Organosolv Lignin Degraded Using SO4/ZrO2 as Catalyst

نویسندگان

  • Shengming Zhang
  • Yan Zhang
  • Liang Liu
  • Guizhen Fang
چکیده

Organosolv lignin degradation was carried out through hydrogenolysis routes with SO4/ZrO2 as the catalyst. Structural characterization and antioxidant activity of organosolv lignin samples were investigated; the antioxidant activity of the organosolv lignin was compared with that of soda lignin. Results showed that the active functional groups contents of organosolv lignin were increased, and the antioxidant activity of organosolv lignin was improved. The total hydroxyl and phenolic hydroxyl group contents of organosolv lignin were increased by 15.81% and 26.55%, respectively, and the Mw was decreased from 5739 g/mol to 4499 g/mol. The IC50 of organosolv lignin on DPPH radicals scavenging rate, ABTS radicals scavenging rate, and reducing power were decreased by 18.91%, 18.08%, and 8.48%, respectively. The catalyzed organosolv lignin can be used as a natural antioxidant for functional food or in cosmetic and polymeric materials.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

In situ stabilization of polypropylene by lignin using a Ziegler-Natta catalyst

A fourth-generation Ziegler-Natta catalyst was prepared to synthesize polypropylene (PP), which was stabilized by in situpolymerization employing lignin as antioxidant. The antioxidant properties of lignin were compared with those of the commercial antioxidant Irganox 1010. The presence of lignin in the reaction medium slightly decreased the catalytic activity of the reaction. The isotacticity ...

متن کامل

Studies on the Vanadium-Catalyzed Nonoxidative Depolymerization of Miscanthus giganteus-Derived Lignin

Lignin samples isolated from Miscanthus giganteus using organosolv processes were treated with vanadium catalysts that were previously developed in our group. We demonstrate that the catalyst with high β-O-4′ bond-cleaving activity in dimeric lignin models was also effective in depolymerizing actual lignin. Molecular weight-lowering was evidenced by gel permeation chromatography (GPC), whereas ...

متن کامل

Selective Gas-Phase Conversion of Glycerol to Acetol Over Promoted Zirconia Solid Acid Catalysts

The vapour phase selective conversion of glycerol to acetol at normal atmospheric pressure in a fixed-bed micro reactor was investigated over SO4 2 and WOx promoted ZrO2 and M-ZrO2 (M = Al2O3 or TiO2) solid acid catalysts. The investigated sulfate and tungstate ion promoted zirconia-based catalysts were prepared by both coprecipitation and impregnation methods and calcined at 923 K. The synthes...

متن کامل

Ethanol Organosolv Pretreatment of Bamboo for Efficient Enzymatic Saccharification

Bamboo is a potential lignocellulosic biomass for the production of bioethanol because of its high cellulose and hemicelluloses content. In this research, ethanol organosolv pretreatment with dilute sulfuric acid as the catalyst was studied in order to enhance enzymatic saccharification of moso bamboo. The addition of 2% (w/w bamboo) dilute sulfuric acid in 75% ethanol had a particularly strong...

متن کامل

Low-Power Microwave Radiation-assisted Depolymerization of Ethanol Organosolv Lignin in Ethanol/Formic Acid Mixtures

Ethanol organosolv lignin separated from bamboo was depolymerized by low-power microwave radiation (~80 W) using ethanol as a swelling agent and formic acid as a hydrogen donor solvent. After increasing the temperature from 100 to 200 °C, the total amount of phenolic compounds in the products increased from 8.1% to 40.8%, and both the weight average molecular weight (Mw) and number average mole...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2015